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Phosphonic systems: 5. Prototropic equilibria of diethyl alkenylphosphonates (1991)

Gerber, J. P. ; Modro, T. A. ; Wagener, C. C. P. ; [et al.]

New York, NY [u.a.] : Wiley-Blackwell

Heteroatom Chemistry 2 (1991), S. 643-649

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ISSN: 1042-7163

Keywords: Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Base-catalyzed prototropic equilibria for nine pairs of diethyl 1- and 2-alkenylphosphonates have been determined. The results, together with those reported elsewhere for three other pairs, demonstrated that the diethoxyphosphoryl group PO3Et2 has only a very weakly stabilizing effect on the adjacent carbon-carbon double bond. The decisive factors are the number of carbon atoms attached to the double bond and the number of hydrogen atoms available for hyperconjugation.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hc.520020606

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