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High temperature decomposition of ethane (1973)

Burcat, Alexander ; Skinner, Gordon B. ; Crossley, Robert W. ; [et al.]

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 5 (1973), S. 345-352

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Measurements of the rate of formation of methane in the thermal decomposition of ethane in dilute mixtures with argon were made by the shock tube technique. Derived values of the rate constant of the dissociation reaction are compared with earlier data of the same type and with recent shock tube data on the combination of methyl radicals. An RRKM calculation correlating all the data is described, from which an Arrhenius equation for the range 1000-1500°K, log k∞ = 16.9 - 89,500/2.3RT, is obtained.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550050305

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