ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The kinetics of the gas-phase decomposition of bicyclo[4.1.0]heptane has been studied over the temperature range of 708-769 K at pressures between 1 and 17 torr. Isomerization to 1-methylcyclohex-1-ene, methylenecyclohexane, and cycloheptene accounts for 96-98% of the primary reaction products and occurs by first-order, homogeneous, nonradical processes. \documentclass{article}\pagestyle{empty}\begin{document}$$ k_{1 - methylcyclohex - 1 - ene3} /s^{ - 1} = 10^{14.98 \pm 0.50} \exp \left( { - 64600 \pm 1700/1.987T} \right) $$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$ k_{1 - methylenecyclohexane} /s^{ - 1} = 10^{15.08 \pm 0.43} \exp \left( { - 65900 \pm 1400/1.987T} \right) $$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$ k_{cyclohexane} /s^{ - 1} = 10^{14.82 \pm 0.28} \exp \left( { - 64900 \pm 1000/1.987T} \right) $$\end{document}
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550050315
