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Comparisons between experimental and calculated rate constants for dissociation and combination reactions involving small polyatomic molecules (1973)

Tsang, Wing

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 5 (1973), S. 947-963

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The experimental results on decomposition and combination reactions involving O3, HNO3, NH3, C2N2, and NO2Cl over extended temperature and pressure ranges are compared with the deductions from RRKM calculations. Quantitative fits of the data over the entire range are possible only if the external (overall) rotations are assumed to be involved in the reactions. Recommended rate constants for the reactions O + O2 + N2 → O3 + N2 and OH + NO2 + N2 → HNO3 + N2 are presented.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550050605

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