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Reaction between nitrous acid and hydrogen peroxide in perchloric acid medium (1977)

Bhattacharyya, P. K. ; Veeraraghavan, R.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 9 (1977), S. 629-640

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A kinetic investigation on the reaction has been carried out in HClO4 medium under different conditions. A spectrophotometric method of estimation of nitrous acid at various time intervals has been employed. The results are interpreted on the basis ofthe following mechanism: The absolute rate constant value of 39.7 M-1 plusmn; s-1 for k4 and the equilibrium constant Keq = 116M-1 for reaction (2) have been evaluated. The activation energy of the overall reaction has also been determined as Ea = 13.2 kcal/mol.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550090411

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