ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The Arrhenius parameters for the reactions and have been measured. Reaction (2a) was generated and studied by the photolysis of tetrachloromethane in the presence of trichlorosilane and reaction(2b) by the photolysis of 1,1,1,-trichlorotrifluoroethane in the presence of trichlorosilane.The measured data are given by the expressions \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{rcl} {{\rm log}_{{\rm 10}} k_{2{\rm a}}} & = & {11.06 - \frac{{8760}}{{4.57T}}} \\ {{\rm log}_{{\rm 10}} k_{2{\rm b}}} & = & {11.18 - \frac{{8980}}{{4.57T}}} \\ \end{array} $$\end{document} .
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550090414
