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The kinetics of radiation induced hydrogen abstraction by CCl3 radicals in the liquid phase: Cyclanes (1981)

Alfassi, Zeev B. ; Feldman, Liviu

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 13 (1981), S. 517-526

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The kinetics of gamma-radiation induced free radicals reactions in carbon tetrachloride solutions of cyclohexane, cyclooctane and cyclododecane were studied in the range of 27-190°C. The activation energies found were in the order c—C6H12 〉 c—C12H24 〉 c—C8H16, which was explained as due to their ring strain which has the same order. The following log k1 was obtained using the known Arrhenius parameters for CCl3 radical recombination:

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550130602

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