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On the photodissociation of nitromethane at 266 nm (1981)

Kwok, H. S. ; He, G. Z. ; Sparks, R. K. ; [et al.]

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 13 (1981), S. 1125-1131

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: In a crossed laser-molecular beam study of nitromethane it was found that the excitation of nitromethane at 266 nm did not yield dissociation products under collision-free conditions. When a small cluster of nitromethane was excited at the same frequency, the product was seen only at energies and masses consistent with the rupture of the van der Waals bond by vibrational predissociation of the excited state.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550131103

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