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Rate constants for the gas-phase reactions of O3 with a series of carbonyls at 296 K (1981)

Atkinson, Roger ; Aschmann, Sara M. ; Winer, Arthur M. ; [et al.]

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 13 (1981), S. 1133-1142

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Rate constants for the gas-phase reactions of O3 with the carbonyls acrolein, crotonaldehyde, methacrolein, methylvinylketone, 3-penten-2-one, 2-cyclohexen-1-one, acetaldehyde, and methylglyoxal have been determined at 296 ± 2 K. The rate constants ranged from 〈6 × 10-21 cm3 molecule-1 s-1 for acetaldehyde to 2.13 × 10-17 cm3 molecule-1 s-1 for 3-penten-2-one. The substituent effects of —CHO and CH3CO— groups on the rate constants are assessed and discussed, as are implications for the atmospheric chemistry of the natural hydrocarbon isoprene.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550131104

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