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Shock-initiated decomposition of tetramethylgermane and the reaction of methyl radicals with toluene (1982)

Dzarnoski, J. ; Ring, M. A. ; O'Neal, H. E.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 14 (1982), S. 279-289

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The shock-initiated decomposition of tetramethylgermane (1078-1242 K) has been found to involve successive elimination of methyl radicals with the rate constant k1 for the first step given by \documentclass{article}\pagestyle{empty}\begin{document}$$ \log k_{\rm 1} {\rm}(s^{- 1}) = {\rm}(17.00 \pm 0.35) - (77.0 \pm 1.9)\theta {\rm kcal/mol} $$\end{document} In the presence of excess toluene the products were CH4 (major), C2H4, and C2H6. Results relevant to the reaction of methyl radicals with toluene compared to methyl radical recombination are discussed.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550140308

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