Electronic Resource
New York, NY
:
Wiley-Blackwell
International Journal of Chemical Kinetics
15 (1983), S. 25-35
ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Rate constants and activation parameters for the acid-catalyzed hydrolysis of eight ring-substituted diazoacetophenones have been measured in three dioxan-water mixtures. An isokinetic relationship applies to the results obtained using a 50% dioxan-water mixture as solvent. Solvent and substituent effects are discussed together with some mechanistic aspects. Substituent constants are reported for the —COCHN2 group.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550150104
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