Electronic Resource
New York, NY
:
Wiley-Blackwell
International Journal of Chemical Kinetics
17 (1985), S. 967-990
ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The origin of autocatalysis in the pyrolysis of methane has been investigated by kinetic modeling. A mechanism is presented that provides good agreement with experimental data at 1038 K and 433 torr into the autocatalytic region. The main causes of autocatalysis are secondary initiation by hydrocarbon products larger than C2H6 and chain radical methylation sequences.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550170905
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