Electronic Resource
New York, NY
:
Wiley-Blackwell
International Journal of Chemical Kinetics
19 (1987), S. 1107-1107
ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Br atoms produced in a microwave discharge react abnormally rapidly with isobutane to produce HBr + t-Butyl. A VLPR study of the system at high Br atom concentration (Br ˜ 1013/cc) between 298 and 363 K permits one to separate the effects of excited atoms, Br* (2P1/2) from ground state atoms, Br (2P3/2). Rate constants for the latter agree well with bromination measurements and permit fixing ΔHƒ2980(tBu) at 9.5 ± 0.5kcal/mol in agreement with earlier work.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550191207
| Library |
Location |
Call Number |
Volume/Issue/Year |
Availability |
