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  • 1
    Electronic Resource
    Electronic Resource
    A kinetic approach for the mechanism of malachite green-peroxydisulphate reaction in aqueous solution (1992)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 24 (1992), S. 41-49 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The oxidation kinetics of malachite green (MG) with peroxydisulphate ion (PDS) were investigated by monitoring the absorbance change at 618 nm, in aqueous solutions under buffered and unbuffered conditions. Under both conditions, the reaction had first order dependence on reductant and a fractional order (one half) dependence on the oxidant. The stoichiometric ratio between MG and PDS was 1:2. The reaction had a negative salt effect. Reaction rates were enhanced under both high or low pH relative to neutral conditions. A plausible mechanism is proposed.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550240106
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