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Kinetics of benzonitrile nitration with mixed acid under homogeneous conditions (1993)

Andreozzi, R. ; Insola, A. ; Aquila, T. ; [et al.]

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 25 (1993), S. 771-776

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Chemical kinetics of benzonitrile nitration with mixed acid is investigated in the temperature range 283-299 K. Pseudo-first-order rate constants are evaluated by means of rate experiments on homogeneous reacting mixtures having large stoichiometric excesses of nitric acid.The second-order kinetic constants for nitronium ion attack to the aromatic substrate are derived on the basis of the assessed nitration mechanism. An activation energy of 604 ± 37 kJ mol-1 is calculated for this reaction step. © 1993 John Wiley & Sons, Inc.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550250907

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