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Improved method for fitting falloff data (1994)

Poole, James S. ; Gilbert, Robert G.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 26 (1994), S. 273-281

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: An extension of the dimensionless treatment of Troe is developed for fitting falloff data from unimolecular and recombination reactions. This method using dimensionless parametrizations derived from accurate numerical solutions of the master equation for system with any type of activated complex and energy transfer probability distribution, is as easily implemented as Troe's method, and allows global fitting of an entire set of pressure- and temperature-dependent rate coefficients. © 1994 John Wiley & Sons, Inc.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550260205

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