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Kinetics and mechanism for oxime formation from 2-quinolinecarboxaldehyde (1996)

Calzadilla, M. ; Malpica, A. ; Diaz, P. M.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 28 (1996), S. 687-691

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Oxime formation from 2-quinolinecarboxaldehyde occurs with rate-limiting carbinolamine dehydration under both acidic and neutral conditions. Carbinolamine dehydration occurs via a transition state bearing a single positive charge, similar to the corresponding reaction for 2-pyridinecarboxaldehyde and unlike the same reaction for 2-, 3-, and 4-formyl-1-methylpyridinium ions and for the conjugate acids of 3- and 4-pyridinecarboxaldehydes. © 1996 John Wiley & Sons, Inc.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.7

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