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Etude de la cinétique d'une réaction de cyclisation simple (1954)

Davies, A. G. ; Davies, Mansel ; Stoll, M.

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 37 (1954), S. 1351-1360

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Details

ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The Arrhenius parameters for the unimolecular lactonisation of the K-salts of the ω-brom-undecanoic and ω-brom-pentadecanoic acids have been determined. It has been shown that the reaction rate depends on the ionisation of the bromine, not on the cyclisation process. The observations have been discussed and, in particular, an explanation in kinetic terms is provided for the minimum yield of cyclic products near C11.

Additional Material: 5 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19540370444

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