ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
In 0.1 to 0.5 M perchloric acid the oxidation by nitrous acid of the two reductones, ascorbic acid and phenyl hydroxytetronic acid, follows the rate law \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm v = k}_{\rm 3}^{{\rm oH}} {\rm [H}^{\rm + }\, {\rm] [HNO}_{\rm 2} {\rm]\, [red}^{\rm o} {\rm]}{\rm .} $$\end{document} k3oH has been determined for both reductones in aqueous dioxan and for ascorbic acid in water.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19600430139