ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
With alkylbenzylamine D-glucose undergoes AMADORI-rearrangement to 1-alkyl-benzylamino-1-deoxy-D-fructose. Catalytic hydrogenolysis of the benzyl group gives rise to 1-alkylamino-1-deoxy-D-fructose (alkyl-fructosamine). In this way, the methyl, ethyl and butyl derivatives of fructosamine have been prepared in crystalline form. With isocyanic acid and rhodanic acid the 1-alkylamino-1-deoxy-D-fructoses are converted into imidazole derivatives, as expected for substances of the α-aminoketone type.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19600430315