ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Aromatic organo-tin compounds ArSnR3 have been synthesized with R = n-butyl and R = i-propyl. Increased bulk of the leaving group results in lower reactivity towards iodine, showing appreciable interactions between the incoming and leaving groups. A peri hydrogen atom induces a secondary steric acceleration, suggesting that the ground state for large R3Sn substituents in 1-naphthyl systems is strained. This agrees with previous reports by EABORN et coll. [14] relating to the corresponding silicon and germanium compounds.
Additional Material:
5 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19640470704