ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
In a heterolytic fragmentation reaction of the type a-b-c-d-X → a-b + c=d + :X the geometry of the d-X bond and that of the electron-donating group a relative to the b-c bond are critical. This follows from a study of solvolysis rates and products of stereoisomeric 1-methyl-4-, -5- and -7-decahydroquinolyl p-toluenesulphonates in 80 Vol.% ethanol.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19670500211