ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The kinetics of the dimerization of propene in organic solvents under the influence of a homogeneous catalyst containing π-tetramethylcyclobutadiene-nickel dichloride and a prereacted mixture of ethylaluminiumdichloride and tri-n-butylphosphin are reported. The primary reaction products are: 2-methyl-1-pentene, 4-methyl-2-pentene (cis/trans), 2,3-dimethyl-1-butene and 2-Hexene (cis/trans) The results are in accordance with a coordinative mechanism on nickel. New results on the reaction between ethylaluminiumdichloride and O, N and P containing electrondonors are also discussed.
Additional Material:
15 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19690520120