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Chemically Induced Dynamic Nuclear Polarization VIII: Thermal decomposition of dibenzoyl peroxides in solution [1] (1971)

Blank, B. ; Fischer, H.

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 54 (1971), S. 905-912

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Details

ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Thermolysis of di-(4-chlorobenzoyl)-peroxide was carried out in the probe of an NMR. spectrometer. The dependence of product distribution and chemically induced dynamic nuclear polarization (CIDNP.) patterns on the concentrations of radical trapping agents gives evidence that the CIDNP. effects are caused by singlet-triplet transitions, dependent on nuclear spin, in transient benzoyloxy/phenyl radical pairs and by the selective formation of radical products from singlet state pairs.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19710540314

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