ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Fluoroorganic Syntheses IV: 1-Fluoro-1-organyl-cyclopropanes and other Cyclopropane Derivatives by Addition of „Successor-Carbenes“Treatment of chlorodifluormethane or dichlorodifluoromethane with methyllithium in the presence of an olefin affords 1-fluoro-1-methylcyclopropanes in fair yields. Depending on the particular reaction conditions, 1,1-difluorocyclopropanes, 1,1-dimethylcyclopropanes and 1-chloro-1-methylcyclopropanes may be obtained as well. Butyllithium and phenyllithium give rise to analogous products.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19750580842