ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Stereochemistry-odor relationships in the 1-decalone series and their oxa-analogs.The olfactory relationships of (-)-(9S,10S)-5,5,9-trimethyl-trans-1-decalone (2a), 6 diasterioisomers in the 11-nordriman-9-one series (2b-g), and 20 racemic 2-oxabicyclo[4.4.0]decanes are reported and correlated with the ‘Triaxial Rule of Odor Sensation’. This rule also is applied to the two internal C(13) acetals derived from (±)-dihydro-γ-ionone as well as to two epimeric C(18) ethers in the labdane series. Syntheses are described for most of the compounds examined.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19760590418