ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reactions of SnCl2 with the complexes cis-PtCl2P2, P=trialkyl and triaryl phosphines and phosphites, in CDCl3 and CD2Cl2 have been studied using 31P and 195Pt NMR. methods. For equimolar amounts of Sn and Pt, products of the type PtCl(SnCl3)P2 are formed with the complex geometry depending on the nature of P. For P=PEt3 and P(OPh)3, further addition of SnCl2 produces trans-Pt(SnCl3)2 complexes. The syntheses of trans-PtCl(SnCl3) (PEt3)2 and trans-Pt(SnCl3)2 (OPh3)2 are described.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19780610530