Electronic Resource
New York, NY
:
Wiley-Blackwell
Helvetica Chimica Acta
67 (1984), S. 1725-1728
ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
γ-Nitro-γ-butyrolactoneBy oxidation of 3-(1-nitro-2-oxocyclohexyl)propanal (1) with KMnO4, besides 3-(1′-nitro-2′-oxocyclohexyl)pripionic acid (2), the complete hydrolysis product 4-oxononanedioic acid (4) and the oxidized semi-hydrolysis product 5-(2-nitro-5-oxotetrahydro-2-furyl)pentanoic acid (3) were formed. The crystalline 3 decomposes at r.t. forming 4 and nitrous gases; its structure was established by X-ray determination.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19840670709
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