ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The absorption band maximum of solvated electrons, λmax(e-s), in 3- or 4-methylcyclohexanols is observed at longer wavelengths (818-837 nm), if the OH group is axial, and at shorter wavelengths (721-723 nm), if it is equatorial. It is surmised that the size of cavity for the solvated electron is larger in the former case and smaller in the latter.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19900730304