ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Fluorescence measurements have been used to follow the build-up of photoproducts during the direct and benzophenone-sensitized irradiation of the title compounds 1-IN, 1-BrN, and 1-ClN (HN = naphthalene). Compounds 1-IN and 1-BrN react by homolytic dissociation through their lowest triplet and singlet excited states, respectively. Compound 1-ClN does not undergo C-Cl bond fission, except through electron transfer in the presence of an amine A, In the absence of this electron transfer, 1-ClN reacts only through substitution and oxidation processes.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19900730609