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  • 1
    Electronic Resource
    Electronic Resource
    Palladium-Catalyzed Ene-Type Cyclizations of Terpenoid 1,6-Enynes (1991)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 74 (1991), S. 517-530 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Palladium-catalyzed ene-type cyclizations of 1,6-enynes 2 yield methylidene-cyclopentane derivatives 3. Removal of protecting groups from 3 furnishes the diols 4 and 5, whose configurations were established by a combination of X-ray and 1H-NMR techniques. The predominant formation of isomers 4 is discussed in the context of two alternative hypothetical mechanisms previously proposed for this type of cyclization.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19910740308
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