ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
On reaction with ‘O’-donors or O2, the synthetic P-450 analogue 2 undergoes O-insertion at a nonactivated C—H bond of the covalently bound substrate. The mechanism of O-insertion with O2 most likely involves homolytic cleavage of the O—O bond followed by O-insertion via radical recombination.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19920750212