ISSN:
0020-7608
Keywords:
Computational Chemistry and Molecular Modeling
;
Atomic, Molecular and Optical Physics
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A detailed algorithm is described that enables an implementation of a general valence bond (VB) method using the Clifford algebra unitary group approach (CAUGA). In particular, a convenient scheme for the generation and labeling of classical Rumer-Weyl basis (up to a phase) is formulated, and simple rules are given for the evaluation of matrix elements of unitary group generators, and thus of any spin-independent operator, in this basis. The case of both orthogonal and nonrothogonal atomic orbital bases is considered, so that the proposed algorithm can also be exploited in molecular orbital configuration interaction calculations, if desired, enabling a greater flexibility for N-electron basis-set truncation than is possible with the standard Gel'fand-Tsetlin basis. Finally, an exploitation of this formalism for the VB method, based on semiempirical Pariser-Parr-Pople (PPP)-type Hamiltonian and nonorthogonal overlap-enhanced atomic orbital basis, and its computer implementation, enabling us to carry out arbitrarily truncated or full VB calculations, is described in detail.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/qua.560410112
