ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
About the Reaction between n-Alkanes and Aluminium Nitrate-nonahydrateThe reaction between n-alkanes (C10—C13) and aluminium nitrate-nonahydrate in the temperature range 353-403 K, time of contact 12 h and mole ratio nitrating agent: hydrocarbon from 1:2 to 2:1 was investigated.The product obtained was separated on silicagel. The fractions separated by adsorption chromatography were studied by i.r.- and combined GC/MS spectroscopy. Only alkyl nitrates were obtained. The oxidation processes yield aldehydes, ketones and nitrate carboxylic acids.The model reaction with n-undecane shows that undecyl-3-nitrate (5), undecanal (6), undeca-5-on (7) and nitrate undecanic acid (8) are obtained.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19863280526
