ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Wittig condensation of (Z)-2-pentenylidene triphenylphosphorane (14) and 7-tert.-butoxy-heptanal (13) under conditions of phase transfer catalysis and subsequent conversion into the corresponding acetate afforded a mixture of 28% 7(E),9(Z)-dodecadien-1-yl acetate, the sex pheromone of Lobesia botrana, along with the other geometrical isomers and 30% unidentified by-products. The synthons 14 and 13 were prepared starting with (Z)-2-butene-1,4-diol (1) and hexane-1,6-diol (9), respectively.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19873290218