ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Neighbouring Group Participation in Electrophilic Additions Initiated by N-BromosuccinimideStarting from endo-5-hydroxymethyl-norbornene as well as 5-(hydroxymethyl)-methyl-cyclohexene the methoxybromination procedure gives cyclic ethers by participation of the hydroxymethyl group. Unsaturated formyl compounds or their acetals, respectively by contrast, gave methoxybromination products. After oxidation of the functional groups bromo methoxy methyl carboxylates are formed depending on the molar ratio of the substrate to NBS.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19873290510