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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The symmetry of D3 h of the trimetaphosphate ion dissolved in H2O or D2O is confirmed by investigation of the infrared spectrum. RAMAN frequencies of crystalline Na3P3O9 · 6 H2O, combined with data from the infrared spectrum and X-ray analysis, show a symmetry of C3 v for the P3O9-ion in the lattice.
    Notes: Die Symmetrie D3 h für das Trimetaphosphation in wäßriger Lösung wird durch Infrarotuntersuchung in H2O und D2O bestätigt, einige frühere Zuordnungen werden richtiggestellt.RAMAN-Aufnahmen an kristallisiertem Na3P3O9 · 6 H2O zeigen eine verminderte Symmetrie im festen Zustand an. Es werden die Infrarotspektren herangezogen und unter Verwendung von Röntgenergebnissen gedeutet. Im Kristall hat das P3O9-Ion die Eigensymmetrie C3 v.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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