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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 320 (1963), S. 78-85 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: From the IR spectrum of „sodium nitrosyl“ prepared by reaction of NO with Na in liquid ammonia, the existence of a dimeric ion N2O22- is derived being not identical with the hyponitrite ion. Of the two possible structures left, the cis form and the „star“ form (with one nitrogen as a central atom), the former is preferred.
    Notes: Aus dem IR-Spektrum des „Nitrosylnatriums“, des Reaktionsproduktes von Stickstoffmonoxid mit Natrium in flüssigem Ammoniak, wird gefolgert, daß ein dimeres Ion N2O22- vorliegt, das mit dem Hyponitrition nicht identisch ist. Von den beiden anderen möglichen Strukturen, der cis-Form und der Stern-Form mit einem zentralen N-Atom-wir der cis-Form der Vorzug gegeben.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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