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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 337 (1965), S. 6-13 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Es wurde die thermische Zersetzung von 16 Übergangsmetall-Pyridinkomplexsalzen der allgemeinen Formeln M(py)4X2 und M(py)2X2 mit Hilfe von TG- und DTA-Messungen untersucht (M und X siehe „Summary“) und gefunden, daß hierbei hauptsächlich eine Pyridinabgabe erfolgt. Übergänge von (py)4- zu (py)2- und von (py)2- zu (py)1-Komplexen wurden beobachtet.
    Notes: The thermal dissociation of 16 pyridine complexes of the general formulas, M(py)4X2 and M(py)2X2, where M is Cu, Ni, Mn, Cd, Zn, and Co and X is SCN, Cl, Br, I and ½ C2O4, was studied by thermogravimetry and differential thermal analysis. The thermal transitions involved were mainly the depyridination reaction to lower pyridine content complexes. Such reactions as tetrakis(pyridine) → bis(pyridine) → mono(pyridine) complexes were observed. The depyridination reactions for the complexes were discussed in detail.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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