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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 353 (1967), S. 216-222 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Dimethylsulfoxid-Komplexe von Seltenerdmetallchloriden, MCl3 · n DMSO mit M = La, Ce, Pr, Nd, Sm, Gd; n = 4 und M = Y; n = 3 wurden dargestellt. Aus den IR-Spektren folgt Koordination über Sauerstoff, aus der Leitfähigkeit in CH3CN, DMSO und DMF die Koordinationszahl 8 für die Lanthaniden und 7 für Yttrium. Es wird eine Cl-verbrückte Struktur vorgeschlagen.
    Notes: Dimethyl sulphoxide complexes of seven rare earth chlorides of the general formula MCl3 · n DMSO where M = La, Ce, Pr, Nd, Sm, or Gd; n = 4 and M = Y; n = 3 have been isolated and characterized. The infrared studies reveal coordination through oxygen. The conductance data in acetonitrile, dimethyl formamide and dimethyl sulphoxide suggest a coordination number of 8 for lanthanons and 7 for yttrium. A bridge-type structure involving chlorine is postulated.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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