ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Li2ZrO3 is monoclinic [a = 5.427; b = 9.025, c = 5.427 Å, β = 112.75°, Z = 4]; space group Cc—C4s[drö = 4.15, dpyk = 4.09 g · cm-3]; all atoms occupy position 4(a); 3-dimensional datas [155 (h 01) - (h 41) and (Okl), R = 6.8%, Mo - Kα]. Li2HfO3 [a = 5.416, b = 8.984, c = 5.394, β = 112.87°, Z = 4] is isotypic[drö = 6.61, dpyk = 6.54 g · cm-3]. Calculations of the MADELUNG Part of lattice Energy (MAPLE) confirm the assumed positions of Li.
Notes:
Li2ZrO3 kristallisiert monoklin [a = 5,42; b = 9,025; c = 5,427 Å, β = 112,75°; Z = 4] in der Raumgruppe Cc—C4s[drö = 4,15; dpyk = 4,09 g · cm-3]. Alle Teilchen besetzen die Punktlage 4(a). 3-dimensionale Einkristalldaten [155 (h 01) bis (h 41) und (Ok1); R = 6,8%; Mo—Kα]. Li2HfO3 [a = 5,416; b = 8,984; c = 5,394 Å, β = 112,87°; Z = 4] ist isotyp [drö = 6,61 und dpyk = 6,54 g · cm-3].Berechnungen des MADELUNG-Anteiles der Gitterenergie (MAPLE) stützen die angenommenen Li-Positionen.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19693710513
