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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 404 (1974), S. 71-75 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Chalkogenolates. LXV. Studies on Thioformic Acids. 8. Crystal Structure of Potassium DithioformatePotassium dithioformate K[HCS2] crystallizes tetragonal within the space groups I4/mem-D184h (no. 140). The cell dimensions are a = 10.596 and c = 7.946 Å; Z = 8.The structure contains sheets of dithioformate ions at z = 0 and 0.5 with sheets of potassium ions half way between parallel the xy-plane. The coordination number of potassium is 8, that of sulfur is 4. Structural refinements by least-squares methods came to a final R = 0.093.
    Notes: Kaliumdithioformiat K[HCS2] kristallisiert tetragonal in der Raumgruppe I4/mcm-D4h18 (Nr. 140). Die Gitterkonstanten betragen a = 10,596 Å und c = 7,946 Å; Z = 8.Die Struktur wird aufgebaut aus sich abwechselnden Schichten von Dithioformiationen bei z = 0 bzw. 0,5 und Kaliumionen bei z = 0,25 bzw. 0,75 parallel zur xy-Ebene. Die Koordinationszhl von Kalium gegenüber Schwefel beträgt 8. Die Struktur wurde bis zu einem R-Wert von 0,093 verfeinert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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