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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 408 (1974), S. 9-14 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation and Vibrational Spectra of N-Trimethylsilyl-Tris(trimethylsiloxy)-Vanadium (V) imine, (Me3SiO)3V=N—SiMe3The preparation of the title compound from VOCl3 and hexamethyl-disilazane is described. The vibrational spectra of the compound suggest a vanadium-nitrogen triple bond and a near linear vanadium-nitrogen-silicon arrangement.
    Notes: Die Darstellung von (Me3SiO)3V=N—SiMe3 aus VOCl3 und Hexamethyldisilazan wird beschrieben. Nach schwingungsspektroskopischen Unter suchungen liegt eine Vanadium-Stickstoff-Dreifachbindung mit nahezu linearer Vanadium-Stickstoff-Silicium-Anordnung vor.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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