ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
On Fluoro…onium Salts. II. Preparation and Spectroscopic Properties of Monofluorophosphonium Fluoroborates and FluoroarsenatesUsing vacuum-line techniques, fluorophosphonium fluoroborates and fluoroarsenates can be readily generated from the corresponding phosphoranes. The new compounds are characterized by their n.m.r. and i.r. spectra.
Notes:
In einer Hochvakuumapparatur können Monofluorphosphonium-fluoroborate und -arsenate, [R2R′PF] (BF4, AsF6) (R = CH3, C6H5, R′ = H, CH3, C6H5) durch Umsetzung der entsprechenden Difluorphosphorane R2R′PF2 mit Bortrifluorid und Arsenpentafluorid in einfacher Weise dargestellt werden. Die neuen Verbindungen werden durch ihre NMR-und IR-Spektren charakterisiert.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19754180310