ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Novel Inorganic Ring Systems. XXVI. The Disila-phospha(V)-diaza-cyclopentane Ring SystemCompounds of the disila-phospha(III)-diaza-cyclopentane ring system react with oxygen, sulphur, selenium, trimethylsilyl azide and tetracarbonyl nickel via oxidative addition or displacement resulting in derivatives of disila-phospha(V)-diaza-cyclopentane. The novel prepared substances are described in their properties and confirmed in their structure by elemental analysis, mass, n.m.r. and vibration spectroscopy.
Notes:
Disila-phospha(III)-diaza-cyclopentane reagieren mit Sauerstoff, Schwefel, Selen, Trimethylsilylazid und Nickeltetracarbonyl unter oxydierender Addition bzw. Verdrängung zu Derivaten eines Disila-phospha(V)-diaza-cyclopentan-Ringsystems. Die neu dargestellten Verbindungen werden in ihren Eigenschaften beschrieben und über Elementaranalysen, Massen-, Kernresonanz- und Schwingungsspektren in ihrer Struktur bestätigt.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19764200206