ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
On Chalcogenolates. 79. Studies on N-Hydroxy Dithiocarbamic Acid. 1. Preparation and Properties of N-Hydroxy Dithiocarbamates and of Hydroxylammonium DithiocarbamateIn the presence of the corresponding hydroxide the reactions between hydroxylamine and carbon disulfide lead to N-hydroxy dithiocarbamates \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm M[S}_{\rm 2} {\rm C - NH - OH] with M = Na, K, Rb, Cs, [H}_{\rm 3} {\rm NOH]} $$\end{document} and [H3NOH][S2C—NH2], respectively.The unstable compounds have been characterized by different methods.
Notes:
Durch Umsetzung von Hydroxylamin mit Kohlenstoffdisulfid in Gegenwart des entsprechenden Hydroxids wurden die N-Hydroxydithiocarbamate \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm M[S}_{\rm 2} {\rm C - NH - OH] mit M = Na, K, Rb, Cs, [H}_{\rm 3} {\rm NOH]} $$\end{document} und [H3NOH][S2C—NH2] hergestellt.Die instabilen Verbindungen wurden mit verschiedenen Methoden charakterisiert.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19774370132