ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Organometal Phosphine Substituted Transition Metal Complexes. XXV. Organoelement(IVb) Phosphine Derivatives of Tetracarbonyl(trimethyltin)cobaltTetracarbonyl(trimethyltin)cobalt reacts with di(tert-butyl)phosphine, tri(tert-butyl)phosphine, di(tert-butyl)chlorophosphine as well as with tris(trimethylgermanium)- and tris(trimethyltin)phosphine with displacement of one CO ligand and formation of the corresponding organoelement(IVb) phosphine substituted tricarbonyl(trimethyltin)cobalt complexes. The i.r., Raman, 1H-n.m.r., and 31P-n.m.r. spectra of the complexes are reported are reported and discussed.
Notes:
Tetracarbonyl(trimethylstannyl)cobalt reagiert mit Di(tert-butyl)phosphin, Tri(tert-butyl)phosphin, Di(tert-butyl)chlorphosphin sowie Tris(trimethylgermyl)- und Tris(trimethylstannyl)phosphin unter Abspaltung eines CO-Liganden und Bildung entsprechender organo-element(IVb)phosphin-substituierter Tricarbonyl(trimethylstannyl)cobalt-Komplexe. Die Infrarot-, Raman-, 1H-NMR- und 31P-NMR-Spektren werden mitgeteilt und diskutiert.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19794580134
