ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Complexes of Chromium, Molybdenum, and Tungsten with Aminoarsanes as LigandsThe aminoarsanes Me2As—NMe2, MeAs(NMe2)2, and As(NMe2)3 form with the carbonyles of the sub-group VI metals complexes of the general formula (CO)5M—L (L = aminoarsane; M = Cr, Mo, W). The cleavage of the As—N bond by reactions with acids HX results in the formation of complexes of the general formula (CO)5M—As(Me2)—X, (CO)5M—As(Me)X2, and (CO)5M—AsX3.
Notes:
Die Aminoarsane Me2As—NMe2, MeAs(NMe2)2 und As(NMe2)3 bilden mit den Carbonylen der Metalle der VI. Nebengruppe Komplexe der allgemeinen Formel (CO)5M—L (L = Aminoarsan; M = Cr, Mo, W). Die Spaltung der As—N-Bindung mit Säuren HX führt zur Bildung von Komplexen der Formel (CO)5M—As(Me2)—X, (CO)5M—As(Me)X2 und (CO)5M—AsX3.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19835071215
