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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Thermal Behaviour of Heteropoly Acids of the Type H3+n[PVnMo12-nO40] · x H2O (n = 0, 1, 2, 3). II. Raman and Infrared Spectroscopic InvestigationsThe investigation of de- and rehydratization of the heteropoly acids H3+n[PVnMo12-nO40] · x H2O (n = 0, 1, 2, 3) shows typical changes in the region of valence and bridging vibrations in the Raman and infrared spectra, in particular during the existence of „anhydrous“ forms. The time dependence of rehydratization is also demonstrated well with a special Raman sample technique.
    Notes: Die Untersuchung der De- und Rehydratisierung der Heteropolysäuren H3+n[PVnMo12-nO40] · x H2O (n = 0, 1, 2, 3) ergibt typische Änderungen im Bereich der Valenz- und Brückenschwingungen in den Raman- und Infrarotspektren, besonders im Existenzbereich der „Anhydride“. Auch die Zeitabhängigkeit der Rehydratisierung läßt sich mit einer speziellen Ramanküvette gut verfolgen.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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