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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 527 (1985), S. 203-207 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Kationische Carbonyl-Ruthenium(II)-Komplexe mit Nitril-LigandenStabile kationische Komplexe vom Typ [RuCO(PPh3)2(L)RCN]+[ClO4]-, mit Acetonitril bzw. Acrylonitril wurden dargestellt. Als zweizähnige Liganden (LH) dienten Acetylaceton, Benzoylaceton, Dibenzoylmethan, Trifluorothenoylaceton und 8-Hydroxochinolin. Die Komplexe wurden analysiert, ferner durch IR-, 1H- und 31P-NMR-, Leitfähigkeits- und ESCA-Messungen charakterisiert; eine Stereochemie erscheint möglich.
    Notes: Stable cationic complexes of the type [RuCO(PPh3)2(L)(RCN)]+[ClO4]- derived from acetonitrile and acrylonitrile have been synthesized. The bidentate ligands (LH) used are acetylacetone, benzoylacetone, dibenzoylmethane, trifluorothenoyl acetone and 8-hydroxyquinoline. The complexes have been characterized by elemental analysis, IR, conductivity, 1H and 31P NMR and ESCA studies, and possible stereochemistry has been established.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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